Summary: Biochar amended storm garden efficacy study, pollution removal in a storm garden amended with biochar, efficacy of biochar amendment in storm garden, cross section of biochar swale, pollution removal rates
Garden Pollutant Removal Efficacy
Effectiveness Study
Interstitial Data Summary Report
September 2023
Prepared By:
City of Spokane
Wastewater Management Department
Garland Avenue Biochar Amended Storm Garden Effectiveness Study
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Introduction
The urban environment is a source of pollutants that stormwater runoff picks up and ultimately carries
with it along its flow path to a receiving water body. Typical pollutants from an urban environment
include phosphate and nitrate (nutrients), copper and zinc (heavy metals), pesticides and cleaners (toxic
chemicals), car fluids (oils and fuels), and sediment (total suspended solids) that are generated by routine
human activities. Without appropriate stormwater management, the pollutants can be transported into
the Spokane River and the Spokane Valley-Rathdrum Prairie (SVRP) Aquifer via stormwater runoff. The
Spokane River is listed on the U.S. Environmental Protection Agency’s (EPA’s) 303d list of impaired water
bodies for heavy metals and nutrient impacts, and the SVRP Aquifer is the major drinking water source
for the region.
Low impact development (LID) methods include the construction of structural best management
practices (i.e. bioretention/bioinfiltration facilities) capture and treat stormwater runoff. Bioretention
and bioinfiltration facilities (stormwater treatment facilities) are typically comprised plants and
engineered soil mixtures that are designed to remove typical urban pollutants from stormwater prior to
infiltration or discharge through an outfall. Regional LID guidance and Washington Department of
Ecology (Ecology) stormwater manuals prescribe a standard soil mixture of sandy soils and compost for
stormwater facility soils for structural best management practices (BMPs). However, recent research
has suggested that phosphorus, nitrogen, and copper can leach from the compost component of
bioretention soil mixes.
Biochar is a form of charcoal that is the lightweight black residue of carbon and ashes that remains after
the pyrolysis of a biomass. It is a carbon-rich material produced from thermal decomposition of biomass
at elevated temperatures with little or no oxygen. Biochar biomass originates from a multitude of
different feed stocks, such as wood or grass, and its’ high surface area and porosity are desirable
characteristics for capturing pollutants, similar to activated carbon.
Stormwater treatment facilities (storm gardens) with the inclusion of biochar in the engineered soil were
constructed on W. Garland Avenue in the City of Spokane in 2014. Monitoring of the stormwater at the
storm gardens began in 2015 in order to study the stormwater treatment potential for urban stormwater
pollutants by the biochar soil mix. To determine the treatment potential of the biochar amended soil
mix, stormwater is sampled before, and after, it interacts with the engineered soil, and the results are
compared in order determine the extent to which pollutants are captured by the soil media.
The Eastern Washington Phase II Municipal Stormwater permit issued by Ecology is the regulatory
document that dictates the stormwater management requirements in the City of Spokane. In order to
satisfy the conditions of Section S8.A of the 2014 issuance of the permit, the Garland Avenue storm
garden site was selected to be an effectiveness study. The Garland Avenue Biochar Amended Storm
Garden Pollutant Removal Efficacy effectiveness study Quality Assurance Project Plan (QAPP) was
approved by Ecology in March 2019, and stormwater monitoring commenced with the May 2019
sampling event accordingly. Stormwater monitoring for the Garland Avenue Storm Garden effectiveness
study will be performed through the spring of 2024.
Garland Avenue Biochar Amended Storm Garden Effectiveness Study
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Project Description
The Garland Avenue Storm Garden effectiveness study site is comprised of a storm garden installed in
the public right of way planting strip (area between the curb line and the sidewalk) on W. Garland Avenue
near the intersection of N. Belt Street. The storm garden is being monitored to determine the treatment
potential of a biochar amended bioretention soil mix for typical urban stormwater runoff pollutants (i.e.
sediment, nutrients, heavy metals, diesel range organics, and oil range organics). The location of the
study area is shown in Figure 1.
Storm water is conveyed overland via roadway to the storm garden, where samples are collected of the
influent prior to infiltrating the storm garden, and of the effluent after it has percolated through the
engineered soil. Laboratory analysis of the influent and effluent samples are used to determine the
treatment efficiency for each pollutant, as well as to monitor trends of the pollutants over time. Figure
2 displays the location of the storm garden and sampler locations.
Figure 1. Location map of Garland Avenue Storm
Figure 2. Storm garden and sampler location map.
Garland Avenue Biochar Amended Storm Garden Effectiveness Study
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The Garland Avenue storm garden was designed utilizing LID principles and constructed with the
inclusion of a wood-based biochar as a component of the engineered bioretention soil mix. The
amended engineered soil mix was emplaced over a drain rock underdrain. The underdrain consists of a
perforated collection pipe installed the drain rock overlying an impermeable geosynthetic liner. Drought
tolerant plant species were planted in the storm garden soils, and bark mulch was used to dress the
surface.
Two Vortox liquid samplers were installed at the ground surface in upstream flow path of the storm
garden, and in the subsurface downstream of bioretention soil mix layer. Stormwater influent is
collected in the shallow sampler prior to interacting with the amended engineered soil, and stormwater
effluent that has percolated through the storm garden collects on the lined underdrain, where it is
conveyed to a effluent sampler. Figures 3 and 4 provide cross sectional views of the storm garden and
sampler installations.
Additional details and discussion on the of the storm garden construction and stormwater sampling
equipment are provided in the Garland Avenue effectiveness study QAPP.
Sample Events
Weather forecasts are monitored daily to identify when a qualifying storm event is likely to occur. The
Garland Avenue effectiveness study QAPP defines the qualifying storm event as consisting of a minimum
of 0.02 inches of precipitation, with less than 0.05 or 0.025 inches occurring during the preceding
antecedent dry period in the wet or dry seasons, respectively. Upon prediction of a qualifying storm
event, clean influent and effluent liquid samplers set to collect the first flush runoff are deployed at their
respective site locations. Following the storm event, the samplers are retrieved and transported to the
Riverside Park Wastewater Reclamation Facility (RPWRF), where the collected influent and effluent are
transferred to appropriate sample containers and shipped to an Ecology approved contract laboratory
under chain of custody. Analysis is performed to determine the influent and effluent concentrations of
total suspended solids, nutrients (NO2, NO3, PO4), total and dissolved heavy metals (As, Ca, Cd, Cu, Mg,
Pb, and Zn), diesel range organics, and oil range organics. Additional details and discussion on the
Figure 3. Storm garden cross section.
Figure 4. Storm garden effluent cross section.
Garland Avenue Biochar Amended Storm Garden Effectiveness Study
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sample criteria and process are provided in the Garland Avenue effectiveness study QAPP. Table 1
provides the dates that samples were collected for analysis during qualifying storm events.
2019
2020
2021
2022
2023
May 15
January 22
January 11
March 14
May 4
August 9
May 30
June 15
April 25
June 8
September 27
June 12
August 21
August 29
October 19
October 10
September 18
December 7
November 5
September 27
December 19
October 22
Table 1. Date of qualifying storm events when samples were collected for analysis.
Data Analysis
The influent and effluent pollutant concentrations are used to calculate the pollutant removal efficiency
of the bioretention soil amended with biochar for the monitored pollutants. Table 2 contains the list of
typical urban stormwater pollutants monitored for this study. Table A-1 and Table A-2 in Appendix A
contain the analytical data for the influent and effluent pollutants monitored during the qualifying storm
events that were sampled.
Pollutant
Pollutant Form
Sediment
Total suspended solids
Nutrients
Phosphorus as P
Inorganic Nitrogen (NO2 + NO3)
Hydrocarbons
Diesel range organics
Oil range organics
Total & Dissolved
Metals
Arsenic
Calcium
Cadmium
Chromium
Copper
Magnesium
Lead
Zinc
Hardness as CaCO3
Table 2. Typical urban stormwater pollutants monitored in this study.
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The pollutant removal efficiency for each pollutant (the percent of pollutant retained by the soi) is
calculated as percent removal from the in flowing stormwater using the following equation:
Pollutant Removal Efficiency (%) = [Pollutant]nf – [Pollutant]Eff
[Pollutant]Inf
× 100
Where,
[Pollutant]Inf = Influent pollutant concentration, and
[Pollutant]Eff = Effluent pollutant concentration.
Percent removals are calculated from the pollutant influent and effluent concentrations for the
pollutants listed in Table 2 in order to obtain pollutant specific treatment efficacies for the biochar
amended soil. Table A-3 in Appendix A contains the percent removal efficiencies for the pollutants
monitored during the qualifying storm events that were sampled. Pollutant removal trend analyses for
each monitored pollutant are provided in Appendix B. Percent removals per each qualifying storm event
sampled for the monitored pollutants are provided in Appendix C.
Results
Review of the analyses show mixed pollutant retention results that appear to depend on the pollutant
and perhaps season. The results seem to vary significantly per event. Between 54 and 73 percent of the
events for the concentrations of total metals showed a net decrease (removal), with the exception of
total calcium. Of the array of dissolved metals, only zinc had a value that was more than half of the
events sampled showing a net decrease in concentration. Dissolved zinc, total suspended solids, and oil
range organics demonstrated that greater than 75% of the sample events had a net decrease in pollutant
concentrations.
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Figure 5. Percent of Events with Net Removal of Pollutant
Path Forward
This study will continue until the spring of 2025, and final determinations will be made on the
performance of the Garland Avenue Storm Gardens with biochar amended soil.
Percent (%)
Total
Dissolved
Appendix A
A-7
Appendix A – Influent and Effluent Data Tables
Appendix A
A-1
Table A-1. Table of 2019 – 2023 Influent Pollutant Concentrations
(std)
Total Metals
Dissolved Metals
TSS
(mg/L)
DRO
(mg/L)
(std)
(mg/L)
Hardness
(mg/L CaCO3)
(mg/L)
Hardness
(mg/L…
